Lighting: evening, so just some mild fluorescent bulbs above subjects
Thoughts: they are low to the ground and I don't want to pull out the umbrellas and the light stands. So I grab the reflector (silver/gold side out for neutral warmth) and grab an SB600 flash with the little plate it comes with for setting down on the ground. I place the SB600 in front of the reflector, pointing directly away from my subjects. Then I grab my SB800 with the diffuser on it and put it on my camera. I am actually about 12 feet away from my subjects, but the SB600 is about 5 feet from them.

Settings: the SB600 is set at TTL (through the lens- basically, this is auto setting, and the camera decides what power to put through it). I've got a long lens on to get close in (shooting from 160mm to 200mm) I am also shooting at f2.8 and 1/80. I chose 2.8 because I am trying some focal depth experiments with my long lens and it lets my flashes work at a lower power. I chose 1/80 because anything slower seems make my subjects movement show up (out of focus).
The SB800 is on 1/124 power (so virtually nothing... just used to fire the SB600) and because I am so far from my subjects, I am essentially just using one flash here.
Fire a couple of shots...


I like the focus on my subjects, but the background is really dark... too dark.
So I increase the power of the SB800 to about 1/2 power (really get some ambient light around them). No other settings changed. (I could have just changed my exposure to 1/20 or 1/15 instead of 1/80, but then I risk out of focus subjects, esp the spontaneous pics I was shooting). Or I could have increased my ISO to 1600, but that's really going to make it grainy with my camera.
So a couple of shots...


So I like the fill light that brought my images.
Parting shot... I really like this one because I like broken light, when it finds its way to your subject

I am shooting these at about F4 and between 1/30 and 1/80 of a second with ISO between 100 and 200 in full Manual mode. I find that I generally get better results with 2 or 3 flashes when I go manual on cameras and manual power on the flashes.
I like not having a shadow behind the subject... to avoid this, increase the intensity of the reflected light (or ambient light with the shutter time being longer) and don't place an object close behind the subject (in the plane of the snoot and subject -hope that made sense